Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/70303
DC FieldValueLanguage
dc.contributor.authorHao, O.Y.en_US
dc.contributor.authorLee, W.H.en_US
dc.contributor.authorShiue, S.T.en_US
dc.contributor.authorLin, T.L.en_US
dc.date2002zh_TW
dc.date.accessioned2014-06-11T05:59:38Z-
dc.date.available2014-06-11T05:59:38Z-
dc.identifier.issn0887-6266zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/70303-
dc.description.abstractSolvent transport in poly(ethylene terephthalate) (PET) and related phase transformation were investigated. The data of mass sorption were analyzed according to Harmon's model for Case I (Fickian), Case II (swelling), and anomalous transport. This transport process in PET is accompanied by the induced crystallization of the original amorphous state. The transformation was examined by wide-angle X-ray scattering, small-angle X-ray scattering, differential scanning calorimetry, and Fourier transform infrared spectroscopy. During this process, the matrix is under a strain state that causes different kinetic paths of crystallization as compared with that by thermal annealing. This state of strain assists the development of the solvent-induced crystallization. The model regarding crystallization was proposed in terms of the study of long period L, the crystal thickness l(c), and the thickness of amorphous layer l(a), obtained from the one-dimensional correlation function and interface distribution function. Different kinetic paths were discovered for different crystallization processes. (C) 2002 Wiley Periodicals, Inc.en_US
dc.language.isoen_USzh_TW
dc.relationJournal of Polymer Science Part B-Polymer Physicsen_US
dc.relation.ispartofseriesJournal of Polymer Science Part B-Polymer Physics, Volume 40, Issue 14, Page(s) 1444-1453.en_US
dc.subjectsolvent-induced crystallizationen_US
dc.subjectPETen_US
dc.subjectmass transporten_US
dc.subjectsmall-angle scatteringen_US
dc.subjectglassy polymersen_US
dc.subjectmechanical deformationen_US
dc.subjectmethanol transporten_US
dc.subjectmelting behavioren_US
dc.subject2-phase systemsen_US
dc.subjectpoly(ethylene-terephthalate)en_US
dc.subjectdiffusionen_US
dc.subjectcrystallinityen_US
dc.subjectmorphologyen_US
dc.titleSolvent-induced crystallization in poly(ethylene terephthalate) during mass transporten_US
dc.typeJournal Articlezh_TW
item.cerifentitytypePublications-
item.grantfulltextnone-
item.languageiso639-1en_US-
item.fulltextno fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeJournal Article-
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