Please use this identifier to cite or link to this item:
|標題:||Conformational analysis of 1,2-di-O-octanoyl-ethylene-glycerol during aggregation||作者:||Lin, G.L.
|關鍵字:||conformational analysis;stereochemistry;micelle;lipid analogue;candida-rugosa lipase;interfacial activation;pancreatic lipase;hydrolysis;complex||Project:||Journal of the Chinese Chemical Society||期刊/報告no：:||Journal of the Chinese Chemical Society, Volume 47, Issue 2, Page(s) 301-306.||摘要:||
Conformational analysis of 1,2-di-O-octanoyl-ethylene-glycerol during aggregation by 600 MHz H-1 NMR is described. In monomeric states, 1,2-di-O-octanoyl-ethylene-glycerol exists in 75% anti-conformer and 25% gauche-conformer. The first critical micelle concentration of 1,2-di-O-octanoyl-ethylene-glycerol is calculated to be 4.5 mM. In micellar states, 1,2-di-O-octanoyl-ethylene-glycerol exists in 25% anti-conformer and 75% gauche-conformer. When the concentration is greater than 10 mM, 1,2-di-O-octanoyl-ethylene-glycerol probably aggregates to become the larger micelle, micelle II. In the second micellar state, 1,2-di-O-octanoyl-ethylene-glycerol only exists in gauche-conformer.
|Appears in Collections:||期刊論文|
Show full item record
TAIR Related Article
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.