Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/70367
DC FieldValueLanguage
dc.contributor.authorLin, G.L.en_US
dc.contributor.authorHwang, C.I.en_US
dc.contributor.authorChouhwang, J.Y.en_US
dc.contributor.authorTsai, H.J.en_US
dc.date2000zh_TW
dc.date.accessioned2014-06-11T05:59:44Z-
dc.date.available2014-06-11T05:59:44Z-
dc.identifier.issn0009-4536zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/70367-
dc.description.abstractA novel scale of steric substituent constant E-s(D) is defined from the correlation of the logarithms of the internal rotation rate (k(r)) at 393 K with Hancock (E-s(c)) steric constant by means of dynamic NMR. In the inhibition of Pseudomona species lipase by 2,2'-bis-(N-substituted carbamoylmethyl)biphenyls (1-8), the logarithms of bi-molecular rate constants are multiply correlated with both the Taft substituent constant sigma* and E-s(D).en_US
dc.language.isoen_USzh_TW
dc.relationJournal of the Chinese Chemical Societyen_US
dc.relation.ispartofseriesJournal of the Chinese Chemical Society, Volume 47, Issue 3, Page(s) 449-454.en_US
dc.subjectconformational analysisen_US
dc.subjectstereochemistryen_US
dc.subjectsteric constanten_US
dc.subjectdynamic NMRen_US
dc.subjectpancreatic cholesterol esteraseen_US
dc.subjectcarbamate inhibitorsen_US
dc.subjectlipaseen_US
dc.subjectsiteen_US
dc.titleConformational analysis of biphenyl derivatives. I. A novel steric constant from the internal rotation rate of 2,2 '-bis-(N-substituted carbamoylmethyl)biphenyl by means of dynamic NMRen_US
dc.typeJournal Articlezh_TW
item.languageiso639-1en_US-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeJournal Article-
item.fulltextno fulltext-
item.grantfulltextnone-
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