Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/70391
標題: Studies on Suzuki-Miyaura Reactions Catalyzed by Ferrocenyl or Cobaltocenyl Phosphines Ligated Palladium Complexes
作者: Hsiao, J.
Weng, C.M.
Hong, F.E.
關鍵字: DFT;Suzuki-Miyaura cross-coupling reaction;Palladium complexes;Ferrocenyl phosphine;Cobaltocenyl phosphine;Secondary phosphine oxide;cross-coupling reactions;effective core potentials;transition-metal;complexes;phosphorus bonded hydrogen;heck reaction;oxidative;addition;c-c;molecular calculations;diphosphine complexes;reductive;elimination
Project: Journal of the Chinese Chemical Society
期刊/報告no:: Journal of the Chinese Chemical Society, Volume 59, Issue 2, Page(s) 161-169.
摘要: 
DFT studies on several dppf- and dppc-derived bidentate phosphines ligated palladium complexes catalyzed Suzuki-Miyaura coupling reactions were pursued. The catalytic reactions employing ligands, having two phosphine biting sites on different cyclpentadienyl or cyclobutadiene rings, such as 1,1'-dmpf or 1,1'-dmpc, have been verified to be energetically more favorable than those on the same ring provided that tetra-coordinated palladium conformations for all transition states and intermediates are maintained. Apart from the purpose of storage, the application of phosphinous acid (R2P(OH)) in Suzuki-Miyaura reaction is inferior to tertiary phosphine (R3P).
URI: http://hdl.handle.net/11455/70391
ISSN: 0009-4536
DOI: 10.1002/jccs.201100342
Appears in Collections:期刊論文

Show full item record
 

Google ScholarTM

Check

Altmetric

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.