Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/70516
DC FieldValueLanguage
dc.contributor.authorTseng, J.M.en_US
dc.contributor.authorChang, R.H.en_US
dc.contributor.authorHorng, J.J.en_US
dc.contributor.authorChang, M.K.en_US
dc.contributor.authorShu, C.M.en_US
dc.date2006zh_TW
dc.date.accessioned2014-06-11T05:59:56Z-
dc.date.available2014-06-11T05:59:56Z-
dc.identifier.issn1388-6150zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/70516-
dc.description.abstractMethyl ethyl ketone peroxide (MEKPO) possesses complex structures which have caused many incidents involving fires or explosions by mixing with incompatible substances, external fires, and others. In this study, reactivities or incompatibilities of MEKPO with inorganic acids (HCl, HNO3, H3PO4 and H2SO4) were assessed by differential scanning calorimetry (DSC) and vent sizing package 2 (VSP2). Parameters obtained by the above-mentioned devices could be readily employed to discuss the runaway reaction, such as onset temperature (T-0), heat of reaction (Delta H-d), time to maximum rate (TMR), maximum self heat rate (dT/dt)(max) adiabatic temperature rise (Delta T-ad), maximum pressure of decomposition (P-max) and so on. Mixing MEKPO with hydrochloric acid resulted in the lowest T-0 among inorganic acids. Nitric acid not only lowered the T-0 but also delivered the highest heat releasing rate or self heat rate (dT/dt), which was concluded to be the worst case in terms of contamination hazards during storage or transportation of MEKPO.en_US
dc.language.isoen_USzh_TW
dc.relationJournal of Thermal Analysis and Calorimetryen_US
dc.relation.ispartofseriesJournal of Thermal Analysis and Calorimetry, Volume 85, Issue 1, Page(s) 189-194.en_US
dc.relation.urihttp://dx.doi.org/10.1007/s10973-005-7360-xen_US
dc.subjectDSCen_US
dc.subjectinorganic acidsen_US
dc.subjectmethyl ethyl ketone peroxide (MEKPO)en_US
dc.subjectrunawayen_US
dc.subjectreactionen_US
dc.subjectvent sizing package 2 (VSP2)en_US
dc.subjectcumene hydroperoxideen_US
dc.subjectdecompositionen_US
dc.subjectcontaminantsen_US
dc.subjectsimulationsen_US
dc.subjectkineticsen_US
dc.subjectdscen_US
dc.titleThermal hazard evaluation for methyl ethyl ketone peroxide mixed with inorganic acidsen_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1007/s10973-005-7360-xzh_TW
item.languageiso639-1en_US-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.fulltextno fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
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