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標題: Poly(N-isopropylacrylamide)-Tethered Silicate Platelets for Colloidal Dispersion of Conjugated Polymers with Thermoresponsive and Photoluminescence Properties
作者: Lan, Y.F.
Hsieh, B.Z.
Lin, H.C.
Su, Y.A.
Chan, Y.N.
Lin, J.J.
關鍵字: side-chains;clay;nanoparticles;water;polymerization;poly(para-phenylene);poly(p-phenylene);polyelectrolytes;montmorillonite;polyfluorenes
Project: Langmuir
期刊/報告no:: Langmuir, Volume 26, Issue 13, Page(s) 10572-10577.
Poly(N-isopropylacrylamide)-tethered nanosilicate platelets (NSP-PNiPAAm) have been synthesized by covalently bonding the polymer onto the surfaces of silicate platelets of nanometer dimension, and this class of nanohybrids has proved to be effective for dispersing water-insoluble conjugated polymers (CPs). Simple pulverization of poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) with NSP-PNiPAAm rendered the powder material dispersible in water, whereupon it displayed thermoresponsive properties at 37.5 degrees C and CP particle size variation between ea, 50 and 100 nm by SEM observation. The same dispersion had a maximum UV-vis absorption at 524 mu and PL emission at 605 nm. The PL emission was significantly higher at 4 degrees C than at 45 degrees C. Being coated as a film, it showed an orange emission under an ultraviolet lamp, consistent with the PL measurement. The water-borne process of dispersing the CP in aqueous media by the presence of NSP-PNiPAAm and followed by film formation to demonstrate a unique method of manipulating hydrophobic conjugated polymers in a facile manner.
ISSN: 0743-7463
DOI: 10.1021/la100616d
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