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標題: Mercury(II) complex of inverted N-methylated porphyrin: HgPh(2-NCH(3)NCTPP)
作者: Peng, C.C.
Yang, F.A.
Chen, J.H.
Wang, S.S.
Tung, J.Y.
關鍵字: mercury;X-ray diffraction;N-inverted N-methylated porphyrin;(1)H;relaxation;chemical-shift anisotropy;confused porphyrin;relaxation;isomer
Project: Polyhedron
期刊/報告no:: Polyhedron, Volume 27, Issue 11, Page(s) 2309-2314.
The reaction of PhHgOAc with 2-NCH(3)NCTPPH (2) gave a mercury(II) complex of (phenylato)(2-N-methyl-5,10.15,20-tetraphenyl-21-carbaporphyrinato-N,N',N '')-mercury(II), [HgPh(2-NCH(3)NCTPP); 7]: the coordination sphere around Hg(1) in 7 was a four-coordinate derivative with a seesaw geometry and dipole-dipole (DD) interaction governed the longitudinal relaxation rate for Hg(1)-Ph-H(2,6) protons of 7 in CDCl(3) (0.01 M) at 599.95 MHz. (C) 2008 Elsevier Ltd. All rights reserved.
ISSN: 0277-5387
DOI: 10.1016/j.poly.2008.04.033
Appears in Collections:期刊論文

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