Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/71386
DC FieldValueLanguage
dc.contributor.authorLi, Q.H.en_US
dc.contributor.authorGau, H.M.en_US
dc.date2012zh_TW
dc.date.accessioned2014-06-11T06:01:18Z-
dc.date.available2014-06-11T06:01:18Z-
dc.identifier.issn0936-5214zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/71386-
dc.description.abstractWe describe a convenient method for the synthesis of terminal allenes from cross-coupling of propargylic bromide with Grignard reagent. The reaction of propargylic bromide with 1.2 equivalents of Grignard reagent mediated by Ni(acac)(2) (2 mol%) and Ph3P (4 mol%) in THF may produce terminal allenes in good yields and high regioselectivities at room temperature.en_US
dc.language.isoen_USzh_TW
dc.relationSynletten_US
dc.relation.ispartofseriesSynlett, Issue 5, Page(s) 747-750.en_US
dc.relation.urihttp://dx.doi.org/10.1055/s-0031-1290365en_US
dc.subjectallenesen_US
dc.subjectnickelen_US
dc.subjectpropargylic bromideen_US
dc.subjectGrignard reagenten_US
dc.subjectcross-couplingen_US
dc.subjectone-pot synthesisen_US
dc.subjecthydride-transfer reactionen_US
dc.subjectaxially chiral allenesen_US
dc.subjectsubstituted allenesen_US
dc.subject1,3-disubstituted allenesen_US
dc.subjectorganic-synthesisen_US
dc.subjectenantioselective synthesisen_US
dc.subjectstereospecific synthesisen_US
dc.subjectasymmetric-synthesisen_US
dc.subjectgeneral-routeen_US
dc.titleSynthesis of Allenes via Nickel-Catalyzed Cross-Coupling Reaction of Propargylic Bromides with Grignard Reagentsen_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1055/s-0031-1290365zh_TW
item.grantfulltextnone-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.languageiso639-1en_US-
item.fulltextno fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
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