Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/71387
標題: Microwave-Assisted Copper-Catalyzed Cross-Coupling Reaction of Alkynes with Aryl Iodides and Vinyl Halides
作者: Tsai, W.T.
Lin, Y.Y.
Wang, Y.J.
Lee, C.F.
關鍵字: microwaves;copper;cross-coupling;alkynes;aryl iodide;synthetic organic-chemistry;palladium-free conditions;terminal;alkynes;olefin metathesis;conjugated enynes;acetylenes;alkynylation;chlorides;solvent;phase
Project: Synthesis-Stuttgart
期刊/報告no:: Synthesis-Stuttgart, Volume 44, Issue 10, Page(s) 1507-1510.
摘要: 
The microwave-assisted, copper-catalyzed coupling of terminal alkynes with aryl iodides and vinyl halides is reported. In general, the reactions are completed in 10-30 min using 2-5 mol% [CuI(xantphos)] as a catalyst to provide the corresponding alkynes and enynes in good to excellent yields. A broad spectrum of aryl iodides, vinyl iodides, and bromides are coupled with aryl- and alkyl alkynes.
URI: http://hdl.handle.net/11455/71387
ISSN: 0039-7881
DOI: 10.1055/s-0031-1290813
Appears in Collections:期刊論文

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