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|標題:||A novel DMAP-promoted oxazolidinethione deacylation. Application for the direct conversion of the initial chiral thioimide aldols to various ester protecting groups||作者:||Su, D.W.
|關鍵字:||aldols;asymmetric induction;catalysts;enolates||Project:||Tetrahedron Letters||期刊/報告no：:||Tetrahedron Letters, Volume 40, Issue 22, Page(s) 4197-4198.||摘要:||
DMAP (4-(dimethylamino)pyridine) promoted nucleophilic cleavage of the initial chiral thioimide aldols can be directed to form various ester protecting groups without causing racemization of the newly created stereocenters. (C) 1999 Elsevier Science Ltd. All rights reserved.
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