Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/71420
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dc.contributor.authorChen, Y.J.en_US
dc.contributor.authorHuang, Y.P.en_US
dc.date2000zh_TW
dc.date.accessioned2014-06-11T06:01:22Z-
dc.date.available2014-06-11T06:01:22Z-
dc.identifier.issn0040-4039zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/71420-
dc.description.abstractChemoselective and efficient oxidation of various sulfides were mediated by Me3SiCl and KO2 in dry acetonitrile at -15 degrees C to afford corresponding sulfoxides in excellent yields without any interference in the presence of ketone, olefin, ether and hydroxyl functionalities and without further oxidation to the sulfones. A trimethylsilylperoxy radical generated in situ from this new process is proposed. (C) 2000 Elsevier Science Ltd. All rights reserved.en_US
dc.language.isoen_USzh_TW
dc.relationTetrahedron Lettersen_US
dc.relation.ispartofseriesTetrahedron Letters, Volume 41, Issue 27, Page(s) 5233-5236.en_US
dc.relation.urihttp://dx.doi.org/10.1016/s0040-4039(00)00828-5en_US
dc.subjectsuperoxideen_US
dc.subjecttrimethylsilyl chlorideen_US
dc.subjecttrimethylsilylperoxy radicalen_US
dc.subjectoxidationen_US
dc.titleChemoselective and efficient oxidation of sulfides to sulfoxides mediated by trimethylsilyl chloride and superoxide via a trimethylsilylperoxy radicalen_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1016/s0040-4039(00)00828-5zh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.fulltextno fulltext-
item.languageiso639-1en_US-
item.grantfulltextnone-
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