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|標題:||First asymmetric synthesis of chiral 1,4-benzodioxane lignans||作者:||Gu, W.X.
|關鍵字:||asymmetric synthesis;1,4-benzodioxane;lignans;neolignan;silybin||Project:||Tetrahedron Letters||期刊/報告no：:||Tetrahedron Letters, Volume 41, Issue 32, Page(s) 6079-6082.||摘要:||
An asymmetric and regioselective total synthesis approach to 1,4-benzodioxane lignans was reported in which (2R,3R)- and (2S,3S)-3-(4-hydroxy-3-methoxyyhenyl)-2-hydroxymethyl-1,4-benzodioxan-6-carbaldehyde were synthesized firstly. A natural 1,4-benzodioxane neolignan was synthesized firstly by the synthesis approach. (C) 2000 Elsevier Science Ltd. All rights reserved.
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