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標題: A facile method for the synthesis of enantiopure alpha-unsubstituted beta-hydroxy esters
作者: Wang, Y.C.
Hwang, J.Y.
Chen, Y.C.
Chuang, S.C.
Yan, T.H.
關鍵字: asymmetric aldol reaction;silyl ketene acetals;achiral aldehydes;enolate
Project: Tetrahedron-Asymmetry
期刊/報告no:: Tetrahedron-Asymmetry, Volume 11, Issue 8, Page(s) 1797-1800.
One-pot deacylation-debromination reactions involving the transesterification of the initial chiral beta-bromo-beta-hydroxy thioimide aldol adducts and subsequent Al-Hg mediated reductive cleavage of the C-Br bond allow for a facile synthesis of enantiopure beta-hydroxy esters. (C) 2000 Published by Elsevier Science Ltd.
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(00)00109-9
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