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標題: New 1,3-amino alcohols derived from ketopinic acid and their application in catalytic enantioselective reduction of prochiral ketones
作者: Li, X.S.
Yeung, C.H.
Chan, A.S.C.
Yang, T.K.
關鍵字: beta-amino alcohols;asymmetric-synthesis;borane;reagents
Project: Tetrahedron-Asymmetry
期刊/報告no:: Tetrahedron-Asymmetry, Volume 10, Issue 4, Page(s) 759-763.
New 1,3-amino alcohols, (1S,2S)- and (1S,2R)-1-hydroxylmethyl-2-amino-7,7-dimethyl bicyclo[2,2,1]heptane (endo-4 and exo-4), were prepared from ketopinic acid via oximation and reduction. The enantioselective borane reduction of prochiral ketones catalyzed by the borane complex of exo-4 was examined. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(99)00043-9
Appears in Collections:期刊論文

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