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|標題:||New 1,3-amino alcohols derived from ketopinic acid and their application in catalytic enantioselective reduction of prochiral ketones||作者:||Li, X.S.
|關鍵字:||beta-amino alcohols;asymmetric-synthesis;borane;reagents||Project:||Tetrahedron-Asymmetry||期刊/報告no：:||Tetrahedron-Asymmetry, Volume 10, Issue 4, Page(s) 759-763.||摘要:||
New 1,3-amino alcohols, (1S,2S)- and (1S,2R)-1-hydroxylmethyl-2-amino-7,7-dimethyl bicyclo[2,2,1]heptane (endo-4 and exo-4), were prepared from ketopinic acid via oximation and reduction. The enantioselective borane reduction of prochiral ketones catalyzed by the borane complex of exo-4 was examined. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.
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