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標題: Total asymmetric synthesis of (7S,9R)-(+)-bisacumol
作者: Li, A.P.
Yue, G.R.
Li, Y.
Pan, X.F.
Yang, T.K.
關鍵字: bisabolane sesquiterpenes;enantioselective reduction;(+)-curcuphenol;(+)-xanthorrhizol;ketones;phenols;alcohol;route
Project: Tetrahedron-Asymmetry
期刊/報告no:: Tetrahedron-Asymmetry, Volume 14, Issue 1, Page(s) 75-78.
A facile stereoselective synthetic route to (7S,9R)-(+)-bisacumol 1 has been achieved. This novel approach derives its asymmetry by employing asymmetric dihydroxylation and CBS reduction processes. The resulting sesquiterpene 1 was produced with highly enantio- and diastereoselectivity. (C) 2003 Elsevier Science Ltd. All rights reserved.
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(02)00759-0
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