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|標題:||Microwave-Assisted Efficient Synthesis of Aryl Thioethers Through CH Functionalization of Arenes||關鍵字:||Microwave;Aryl thioether;Iridium;Copper;CH functionalization;Arene||Project:||Synlett, Volume 24, Issue 17, Page(s) 2320-2326.||摘要:||
Microwave-assisted iridium-catalyzed meta C-Hborylation followed by copper-promoted C-S bond couplingreactions in one-pot is reported. This approach enables thesyntheses of aryl thioethers in short reaction times (within 2.5h). The system shows good functional group compatibility, aschloro, trifluoromethyl, fluoro and pyridine groups aretolerated by the reaction conditions. Both aryl- and alkyl thiolsare coupled smoothly. The products were formed with excellentregioselectivity in meta position.
|Appears in Collections:||化學系所|
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