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標題: Unexpected Cyclization During the Mitsunobu Reaction of d-Talose Derivatives
關鍵字: Mitsunobu reaction;tetrahydroxy;LCB;d;talose;­nucleosides;cyclization
Project: Synlett, Volume 24, Issue 4, Page(s) 522-526.
A d-talose derivative underwent unexpected cyclization during a Mitsunobu reaction. A plausible pathway for the reaction involves an attack of the nucleophilic azide on the benzyl ring by intramolecular cyclization with loss of the benzyl group. These newly formed, unexpected compounds may be used in the synthesis of ­derivatives of C-nucleosides.
DOI: 10.1055/s-0032-1318196
Appears in Collections:化學系所

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