Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/90469
標題: AC impedance study of vanadium doped oxide glasses containing different ions
不同離子對釩氧化物玻璃交流阻抗影響的研究
作者: Chung-Jun Lin
林宗俊
關鍵字: 釩氧化物玻璃;polaron
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摘要: 
本實驗主要研究xMO-(50-x)V2O5-50P2O5玻璃系統中離子與極化子(Polaron)的導電機制,其中MO為CaO、ZnO、Na2O、Ag2O,x=10、20、30mol%。我們利用X-ray粉末繞射儀檢驗樣品是否為玻璃,再使用交流阻抗分析儀量測玻璃在不同溫度下各頻率的阻抗。交流阻抗分析儀所量測的複數阻抗經由等效電路與複數非線性最小平方法擬合了解帶電載子導電機制,載子的導電機制由Kohlrausch-Williams-
Watts衰退函數來擬合實驗結果,量測樣品在各溫度下的弛豫時間(τ)與去耦合參數(β)所測得的數據分析研究,比較V2O5的極化子在不同組成玻璃在不同環境下的傳導性質。
URI: http://hdl.handle.net/11455/90469
Rights: 同意授權瀏覽/列印電子全文服務,2014-01-24起公開。
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