Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/90474
標題: Fabrication and characteristics of CuSCN solid-state Pb-Sb-S semiconductor-sensitized solar cells
CuSCN固態Pb-Sb-S半導體敏化太陽能電池的製作與特性
作者: Wei-Zhi Lin
林威志
關鍵字: 固態半導體太陽能電池;Solid-stste semiconductor-sensitized solar cells
引用: 參考文獻 [1] B. O'regan , M.Gr?tzel, Nature 353,737-740 (1991) [2] Nadya Anscombe,Nature Photonics 5,266-267(2011) [3] Michael. Gr?tzel, Nature, 414, 338-344(2001) [4] A. Yella, H. W. Lee, H. N. Tsao, C. Yi, A. K. Chandiran, Md.K. Nazeeruddin, E. W. G. Diau, C. Y. Yeh, S.M Zakeeruddin, M. Gr?tzel, Science 334, 629-634(2011) [5] S. H. Im, C. S. Lim, J. A. Chang, Y. H. Lee, N. Maiti, H. J. Kim, Md. K. Nazeeruddin, M. Gr?tzel, S. I. Seok, Nano Letters 11, 4789-4793(2011) [6] Julian Burschka,Norman Pellet,Soo-Jin Moon,Robin Humphry-Baker,Peng Gao,Mohammad K. Nazeeruddin, Michael Gr?tzel,Nature499,316-319(2013) [7] 劉俊傑, 國?中興大學物理所碩士?文 (2013) [8] M. M. Lee, J. Teuscher, T. Miyasaka, T. N. Murakami, and H. J. Snaith, Science 338, 643 (2012). [9] 顏志豪, 國?中興大學物理所碩士?文 (2013) [10] 陳佳靜, 國?中興大學物理所碩士?文 (2008) [11] AuttasitTubtimtae, 國立中興大學物理學研究所博士學位論文, (2011). [12] B.O'Regan, D. T. Schwartz, Chemistry of Materials 10, 1501-1505(1998). [13] B.O'Regan, F.Lenzmann, R.Muis, and J.Wienke, Chemistry of Materials 14, 5023-5028(2002). [14] 顏志豪, 國?中興大學物理所碩士?文 (2013) [15] A Tubtimtae, K. L. Wua, H. Y. Tung, M. W. Lee, G. J. Wang, Electrochemistry Communications 12, 1158-1162 (2010). [16] D. R. Baker, P. V. Kamat, Advanced Functional Materials 19, 805-809 (2009). [17] C. H. Chang, Y. L. Lee, Applied Physics Letters 91, 053503 (2007). [18] J. H. Im, C. R. Lee, J. W. Lee, S. W. Park, and N. G. Park, Nanoscale 3, 4088 (2011). [19] J. H. Im, C. R. Lee, J. W. Lee, S. W. Park, and N. G. Park, Nanoscale 3, 4088 (2011). [20] R. D. Schaller, V. I. Klimov, Physical Review Letters92, 18(2004) [21] 蔡進譯, 物理雙月刊二十七卷五期 (2005) [22] 陳頤承, 郭昭顯, 陳俊亨, 工業材料雜誌258期(2008) [23] The path length in units of Air Mass, changes with the zenith angle.'[online]available http://www.newport.com/Introduction-to-Solar-Radiation/411919/103 3/content.aspx [24] 李德龍, 國?中興大學物理所碩士?文 (2007) [25] 林美佳, 國?中興大學物理所碩士?文 (2011) [26] 李英豪, 逢甲大學化學工程系碩士論文(2008) [27] 蔡進譯, 物理雙月刊二十七卷五期 (2005) [28] L. Kavan, M.Gr?tzel, ElectrochimicaActa 40, 643 (1995). [29] H. J. Snaith, M.Gr?tzel, Advanced Materials 18, 1910 (2006). [30] 顏志豪, 國?中興大學物理所碩士?文 (2013) [31] K. Govardhan Reddy , T. G. Deepak , G. S. Anjusree , Sara Thomas , SajiniVadukumpully , K. R. V. Subramanian , Shantikumar V. Nair and A. Sreekumaran Nair ,Phys. Chem. Chem. Phys.,2014, 16, 6838-6858 [32] Murat Mesta, Marco Carvelli, Rein J. de Vries, Harm van Eersel, Jeroen J. M. van der Holst, Matthias Schober, Mauro Furno, Bj?rn L?ssem, Karl Leo, Peter Loebl, Reinder Coehoorn ,Peter A. Bobbert,Nature Materials 12,652–658 (2013) [33] TayebehAmeri, Jie Min, Ning Li, Florian Machui, DeryaBaran, Michael Forster, Kristina J. Schottler, Daniel Dolfen, UllrichScherf,Christoph J. Brabec,Advanced Energy MaterialsVolume 2, Issue 10, pages 1198–1202, (2012) [34] C. Liu, W. Wu, K. Liu, M. Li, G. Hu, and H. Xu, CrystEngComm14, 6750 (2012). [35] 楊惟智,國?中興大學物理所碩士?文 (2013)
摘要: 
本研究主題為固態PbSbS半導體敏化太陽能電池。固態太陽能電池的製程依序為噴霧熱解法合成blocking-layer,接著spin-coating多孔隙TiO2薄膜,接下來以連續離子沉積法,在TiO2表面分別鍍上PbSbS半導體做為敏化劑,最後填充CuSCN,在表面形成over layer並濺鍍金電極。完成後的樣品經過穿透光譜分析能隙,表面輪廓儀量測薄膜厚度,冷場發射掃描電子顯微鏡分析斷面結構,功率轉換效率,分析太陽能電池的光電轉換效率。表現最佳的PbSbS半導體敏化太陽能電池,效率為0.592%,短路電流4.08 mA/cm2,開路電壓0.43V,填充因子33.74%。

This thesis presents the solid-state PbSbS semiconductor-sensitized solar cell. The solid-state solar cell is fabricated layer by layer as below. First, the blocking layer is deposited on FTO by hot-spray method. Then, the mesoporous-TiO2 layer is spin-coated above. Sensitizers are deposited on the mesoporous-TiO2. The hole transport material fill into the mesoporous-TiO2 and form over layer above. Finally the Au electrode is sputtered on over layer as the electron collector. The morphology of the cell is analyzed by field emission scanning electron microscope. The transmission spectrum is characterized by UV-visible spectrophotometer. The thickness of the film is measured by the surface profiler. I-V characteristics are measured by Keithley 2400 source meter. The best PbSbS-sensitized solar cell yields short circuit current of 4.08 mA/cm2, an open circuit voltage of 0.43 V, a fill factor of 33.74% and a power conversion efficiency of 0.592 % under full sun.
URI: http://hdl.handle.net/11455/90474
Rights: 同意授權瀏覽/列印電子全文服務,2014-08-31起公開。
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