Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/97861
標題: 自發高有序之仿生表面皺褶型態製備
Spontaneous Formation of Stable Aligned Wrinkles
作者: 陳明雄
Ming-Shiung Chen
關鍵字: 皺褶;有序性;濕式製程;wrinkle;well-ordered;wet approach
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摘要: 
高有序與大面積表面皺褶微結構之製備於近幾年中一直是個備受挑戰的課
題,本研究計畫建構於仿生(biomimetic)的概念,建立一新穎性濕式製程的方式, 結合材料化學反應,來製備具高規則排列與大面積的表面皺褶(wrinkle)型態,以期應用於拉伸式光電元件與乾式吸附等應用。本研究開發一新穎濕式製程,透過選擇一水溶性高分子做為犧牲層,緊接著依序將硬質材料與軟性基材,如矽膠(PDMS)披覆於高分子犧牲層上,將整體材料至於水相中使高分子犧牲層緩慢溶解,於溶解過程中會形成一穩定且持續性的應力累積,使材料表面皺褶化(wrinkling),透過材料軟硬度與塗佈製程的控制,使自發產生的皺褶型態具有高規則排整而具有光子晶體的特性,此一濕式製程不需高真空設備,具低成本、便利性與大面積製備等特性,利於工業發展,於軟性電子元件與仿生電子皮膚具有極大的應用潛力。

Here, we develop a new 'wet approach' for the design of skin-like, large-area, and well-ordered polymer-based nanohybrids materials with photonic crystal property. Wrinkles or folds appear when skin is deformed due to muscle contraction or some outside mechanical deformation; they disappear after the deformation is removed. This latter phenomenon is a type of mechanical instability that develops in response to the applied stress (thermal, mechanical, or osmotic), showing unique, periodic surface patterns. By combination of polymer self-assembly and wrinkling, highly ordered lamellar polymer-based wrinkle morphology will be fabricated after releasing stress. Their wavelength and amplitude could be controlled by tuning their thickness and hardness degree. As a result, the wrinkle nanohybrids with flexible and stretchable characters should give the potential applications for sensing and mechanical devices such as mechanochromic sensors, surface enhanced Raman scattering, and gecko-like adhesives.
URI: http://hdl.handle.net/11455/97861
Rights: 同意授權瀏覽/列印電子全文服務,2021-08-23起公開。
Appears in Collections:材料科學與工程學系

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