Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/97952
標題: 磺酸化幾丁聚醣/聚吡咯/帶狀奈米石墨烯奈米複合材料之性質研究及電化學分析
Preparation and Characterization of Sulfonated chitosan/ Polypyrrole/ Graphene nanoribbons Nanocomposite
作者: 張翰文
Hen-Wen Zhang
關鍵字: 聚吡咯;帶狀奈米石墨稀;多巴胺;感測器;Polypyrrole;Graphene nanoribbons;dopamine;sensor
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摘要: 
本研究藉由化學法切割奈米碳管制備帶狀奈米石墨烯,並利用原位聚合法使聚吡咯包覆帶狀奈米石墨烯,形成聚吡咯/帶狀奈米石墨烯複合材料,並和幾丁聚醣或磺酸化幾丁聚醣容液混合滴鑄於玻璃碳電極表面形成修飾層,探討修飾電極之電化學表現。

首先,討論聚吡咯/帶狀奈米石墨烯基本性質,藉由傅立葉紅外線光譜儀(FTIR)觀察聚吡咯特徵峰隨帶狀奈米石墨烯添加量改變之情況,再藉由掃描式電子顯微鏡(SEM)及穿透式電子顯微鏡(TEM)觀察複合材料表面形貌,發現聚吡咯顆粒大小隨帶狀奈米石墨烯添加量增加而下降;在電化學測試部分,分別以幾丁聚醣及磺酸化幾丁聚醣混合聚吡咯/帶狀奈米石墨烯複合材料修飾玻璃碳電極,以循環伏安法(CV)在100mV掃描速率下偵測多巴胺,以幾丁聚醣(CHI)作為固定膜之修飾電極對多巴胺之氧化峰電流值隨帶狀奈米墨烯添加量上升而增加,由聚吡咯(CHI/PPy)的25.44μA上升到帶狀奈米石墨烯添加量5wt%(CHI/5PG)的48.3μA,而磺酸化幾丁聚醣(sCHI)部分則由聚吡咯(sCHI/PPy)的42.5μA上升到sCHI/5PG的67μA,幾丁聚醣經磺酸化後多巴胺氧化電流由原本的48.3μA上升到67μA。

再以微分脈衝伏安法(DPV)觀察多巴胺濃度和電流間關係,CHI/5PG修飾電極在50 -1000 μM的濃度區間內呈現性關係,靈敏度為0.2659 μAcm-2μM-1;sCHI/ 5PG修飾電極之線性範圍為5-500 μM靈敏度為0.8558 μAcm-2μM-1,幾丁聚醣經磺酸化後,偵測多巴胺的靈敏度由原本的0.2659 μAcm-2μM-1上升到0.8558 μAcm-2μM-1增加3倍左右。本研究發現,隨著GNR的添加有助於提升複合材料電化學性質,幾丁聚醣經磺酸化後能有效提高整體修飾電極對多巴胺的氧化還原能力,成功將聚吡咯/帶狀奈米石墨稀複合材料修飾於電極作表面並應用於多巴胺感測。
URI: http://hdl.handle.net/11455/97952
Rights: 同意授權瀏覽/列印電子全文服務,2021-09-25起公開。
Appears in Collections:材料科學與工程學系

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