Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/99100
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dc.contributor.authorLi, Yuan-Hanzh_TW
dc.contributor.authorWang, Sue-Leinzh_TW
dc.contributor.authorSu, Yu-Chiazh_TW
dc.contributor.authorKo, Bao-Tsanzh_TW
dc.contributor.author柯寶燦zh_TW
dc.contributor.authorTsai, Chen-Yenzh_TW
dc.contributor.authorLin, Chia-Herzh_TW
dc.date2018-07-17-
dc.date.accessioned2019-10-02T05:48:39Z-
dc.date.available2019-10-02T05:48:39Z-
dc.identifier.urihttp://hdl.handle.net/11455/99100-
dc.description.abstractFour new 2D indium metal-organic frameworks (MOFs) (Me2NH2)[In(SBA)2] (1), (Me2NH2)[In(SBA)(BDC)] (2), (Me2NH2)[In(SBA)(BDC-NH2)] (3), and (NH4)3[In3Cl2(BPDC)5] (4), (H2SBA = 4,4'-sulfonyldibenzoic acid; H2BDC = 1,4-benzenedicarboxylic acid; H2BDC-NH2 = 2-amino-1,4-benzenedicarboxylic acid; H2BPDC = 4,4'-biphenyldicarboxylic acid) have been synthesized under solvothermal reaction conditions for compounds 1 to 3 and the DES (deep eutectic solvent) reaction has been attempted for compound 4. The structure of these MOFs has been determined by using single crystal X-ray diffraction study and all of theses four 2D monolayer framework with porous properties. The N2 gas sorption measurements indicated that Brunauer-Emmer-Teller (BET) and Langmuir surface areas of compound 1 are 207 and 301 m2 g-1, respectively, which is probably the first one having substantial gas uptake properties in the entire 2D In-MOF family to date. Furthermore, these new indium MOFs on the addition of n-Bu4NBr were active for the cycloaddition of CO2 and propylene oxide, generating propylene carbonates in high conversions under mild conditions. Particularly, the most active MOF 4 was found to efficiently couple CO2 with a series of terminal epoxides to give the corresponding cyclic organic carbonates with high selectivities.zh_TW
dc.language.isoenzh_TW
dc.relationDalton transactions (Cambridge, England : 2003), Volume 47, Issue 28, Page(s) 9474-9481.zh_TW
dc.relation.urihttps://pubs.rsc.org/en/content/articlelanding/2018/dt/c8dt01405azh_TW
dc.titleMicroporous 2D indium metal-organic frameworks for selective CO2 capture and their application in the catalytic CO2-cycloaddition of epoxideszh_TW
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1039/c8dt01405azh_TW
dc.awards2018zh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.fulltextwith fulltext-
item.languageiso639-1en-
item.grantfulltextrestricted-
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