Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/99106
標題: [Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite
作者: Richardson, Paul
Hsu, Ting-Jung
Kuo, Che-Jung
Holmberg, Rebecca J
Gabidullin, Bulat
Rouzières, Mathieu
Clérac, Rodolphe
Murugesu, Muralee
Lin, Po-Heng
林柏亨
Project: Dalton transactions (Cambridge, England : 2003), Volume 47, Issue 37, Page(s) 12847-12851.
摘要: 
Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R3[combining macron] space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed.
URI: http://hdl.handle.net/11455/99106
DOI: 10.1039/c8dt02609b
Appears in Collections:化學系所

Files in This Item:
File Description SizeFormat Existing users please Login
111.pdf1.08 MBAdobe PDFThis file is only available in the university internal network    Request a copy
Show full item record
 

Google ScholarTM

Check

Altmetric

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.