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|標題:||[Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite||作者:||Richardson, Paul
Holmberg, Rebecca J
|Project:||Dalton transactions (Cambridge, England : 2003), Volume 47, Issue 37, Page(s) 12847-12851.||摘要:||
Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R3[combining macron] space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed.
|Appears in Collections:||化學系所|
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