Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/99109
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dc.contributor.authorLiao, Yen-Senzh_TW
dc.contributor.authorLiang, Chien-Fuzh_TW
dc.contributor.author梁健夫zh_TW
dc.date2018-
dc.date.accessioned2019-10-02T08:22:24Z-
dc.date.available2019-10-02T08:22:24Z-
dc.identifier.urihttp://hdl.handle.net/11455/99109-
dc.description.abstractIn this paper, we report an efficient synthetic method for thioester formation from sodium thiosulfate pentahydrate, organic halides, and aryl anhydrides. In the one-pot two-step reactions developed in this study, sodium thiosulfate was used as the sulfur surrogate for acylation with anhydrides, followed by substitution with organic halides through the in situ generation of thioaroylate. Furthermore, two important organic compounds could be successfully synthesized using our developed method. The advantages of the one-pot two-step reactions are operational simplicity, structurally diverse products with 42%-90% yields, use of relatively low toxic and odourless reagents, and easy applicability to large-scale operation.zh_TW
dc.language.isoenzh_TW
dc.relationOrganic & biomolecular chemistry, Volume 16, Issue 11, Page(s) 1871-1881.zh_TW
dc.relation.urihttps://www.ncbi.nlm.nih.gov/pubmed/29473084zh_TW
dc.titleOne-pot synthesis of thioesters with sodium thiosulfate as a sulfur surrogate under transition metal-free conditionszh_TW
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1039/c8ob00178bzh_TW
dc.awards2018zh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.fulltextwith fulltext-
item.languageiso639-1en-
item.grantfulltextrestricted-
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