Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/99208
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dc.contributor.authorSathesh, Venkatesanzh_TW
dc.contributor.authorChen, Jem-Kunzh_TW
dc.contributor.authorChang, Chi-Jungzh_TW
dc.contributor.authorAimi, Junkozh_TW
dc.contributor.authorChen, Zong-Chengzh_TW
dc.contributor.authorHsu, Yu-Chihzh_TW
dc.contributor.authorHuang, Yi-Shenzh_TW
dc.contributor.authorHuang, Chih-Fengzh_TW
dc.contributor.author黃智峯zh_TW
dc.date2018-08-02-
dc.date.accessioned2019-11-06T02:25:12Z-
dc.date.available2019-11-06T02:25:12Z-
dc.identifier.urihttp://hdl.handle.net/11455/99208-
dc.description.abstractThe synthesis of novel branched/star copolymers which possess unique physical properties is highly desirable. Herein, a novel strategy was demonstrated to synthesize poly(ε-caprolactone) (PCL) based miktoarm star (μ-star) copolymers by combining ring-opening polymerization (ROP), styrenics-assisted atom transfer radical coupling (SA ATRC), and atom transfer radical polymerization (ATRP). From the analyses of gel permeation chromatography (GPC), proton nuclear magnetic resonance (¹H NMR), and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS), well-defined PCL-μ-PSt (PSt: polystyrene), and PCL-μ-PtBA (PtBA: poly(tert-butyl acrylate) μ-star copolymers were successfully obtained. By using atomic force microscopy (AFM), interestingly, our preliminary examinations of the μ-star copolymers showed a spherical structure with diameters of ca. 250 and 45 nm, respectively. We successfully employed combinations of synthetic techniques including ROP, SA ATRC, and ATRP with high effectiveness to synthesize PCL-based μ-star copolymers.zh_TW
dc.language.isoenzh_TW
dc.relationPolymers, Volume 10, Issue 8zh_TW
dc.subjectatom transfer radical polymerizationzh_TW
dc.subjectmiktoarm star copolymerszh_TW
dc.subjectring-opening polymerizationzh_TW
dc.subjectstyrenics-assisted atom transfer radical couplingzh_TW
dc.titleSynthesis of Poly(ε-caprolactone)-Based Miktoarm Star Copolymers through ROP, SA ATRC, and ATRPzh_TW
dc.typeJournal Articlezh_TW
dc.identifier.doi10.3390/polym10080858zh_TW
dc.awards2018zh_TW
item.grantfulltextrestricted-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.fulltextwith fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
Appears in Collections:化學工程學系所
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